Activated Metals in Organic Synthesis
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activated metals
advanced organic mechanisms
Alkaline Earth Metal Atoms
Alkyl Halides
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Barbier Reaction
Carbonyl Compounds
Carbonyl Coupling
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Chromium Atoms
cyclization reactions
depassivation
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graduate level chemistry
Grignard Reagents
Homoallylic Alcohols
Intercalation Compounds
laboratory reduction methods
Low Valent Titanium
Low Valent Titanium Reagent
McMurry Coupling
McMurry Reaction
Metal Atoms
Metal Powders
Metal Vapor
metal vapor synthesis
metal-induced reductive method
metal-mediated carbonyl coupling reactions
organic synthesis
organic transformation
organometallic chemistry
Reductive Coupling
Reductive Dimerization
Reformatsky Reactions
Samarium Metal
Set Process
Tetraphenyl Ethylene
Titanium Reagents
Transition Metal Atoms
Transition Metals
Product details
- ISBN 9780849378638
- Weight: 534g
- Dimensions: 156 x 234mm
- Publication Date: 18 May 1993
- Publisher: Taylor & Francis Inc
- Publication City/Country: US
- Product Form: Hardback
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Activated Metals in Organic Synthesis discusses fundamental principles of the generation of activated, highly reactive metals, and their applications in organic synthesis. Following an introductory chapter on basic forms of metals the chapters in Part 1 are devoted to common strategies utilized for the preparation of active metals. These strategies include vaporization and subsequent co-condensation of metal atoms, in addition to depassivating methods employed commonly in laboratory syntheses. Chapters in Part 2 discuss relevant organic transformations in which metal activation plays a crucial role. Specific topics covered include metal-induced reductive methods; pinacolic, Reformatsky-, and Barbier-type reactions; McMurry ketone-olefin coupling; and the Bernet-Vasella reaction. Each chapter is followed by literature citations ranging from specific references to significant reviews. Many structural formulas are provided, making it easy to follow each synthesis. The book will be an important reference for students, organic chemists, and researchers in all areas of organometallic chemistry.
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