Concerted Organic and Bio-Organic Mechanisms
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A01=Andrew Williams
advanced organic reaction mechanism analysis
Aspartyl Proteases
Author_Andrew Williams
Azide Ion
Bio-organic reactions
Bond Fission
Carbenium Ion
Carbenium Ion Intermediates
Carbonyl Centre
Category=PNN
Category=PSB
Category=PSE
Claisen Rearrangement
Concerted Mechanism
Concerted mechanisms
E1cB Mechanism
enzyme catalysis
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eq_isMigrated=2
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General Acid Catalysis
Hydride Ion Transfer
Iminium Ion
Isotope Effects
Kinetic Isotope Effect
Low Barrier Hydrogen Bonds
mechanistic studies
molecular mechanisms
Non-bridging Oxygens
Organic chemistry
organic reaction pathways
Oxocarbenium Ion
Phenolate Ions
Phenyl Allyl Ether
Primary Isotope Effects
Proton Transfer
reaction kinetics
Saturated Carbon
Tetrahedral Adduct
Tetrahedral Intermediate
Transition State Structure
transition state theory
Product details
- ISBN 9780849391439
- Weight: 710g
- Dimensions: 156 x 234mm
- Publication Date: 27 Oct 1999
- Publisher: Taylor & Francis Inc
- Publication City/Country: US
- Product Form: Hardback
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The concept of concerted mechanisms was formulated nearly 90 years ago and virtually all general organic chemistry texts mention it. Until now, however, no monograph has addressed the concept explicitly. Over the last two decades, substantial advancements made in the development of precise methods for elucidating concerted mechanisms have heightened the need for a comprehensive text on the subject.
Concerted Organic and Bio-organic Mechanisms gathers the salient materials related to this emerging field into a single text. It sets forth the precise definition of concertedness-along with working sub-definitions-and describes rigorous experimental tools chemists can use to diagnose the existence or absence of concerted mechanisms.
Advances in our understanding of concerted mechanisms lead to further questions. Concerted Organic and Bio-organic Mechanisms provides the background and the tools researchers need to consider these important questions and further advance the frontiers of reactions, synthesis, and catalysis.
