Isotope Effects In Chemistry and Biology
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advanced isotope effect applications
atmospheric isotope analysis
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Chemical Shift
constant
coordinate
Deuterium Isotope Effects
Double Proton Transfer
energy
enzyme reaction mechanisms
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Equilibrium Isotope Effects
Fractionation Factors
hydrogen bonding dynamics
Hydrogen Bonds
Hydrogen Tunneling
Intrinsic Isotope Effect
Isotope Effects
Isotope Fractionation
isotope separation
Isotopic Composition
Kcal Mol
kinetic
Kinetic Isotope Effects
Low Barrier Hydrogen Bonds
NMR Chemical Shift
organometallic reaction studies
physical chemistry
potential
Primary Isotope Effect
Proton Inventory
Proton Transfer
PT Reaction
rate
reaction
Reaction Coordinate
Reduced Partition Function Ratio
Secondary Isotope Effect
site
Solvent Isotope Effect
surface
Tetrahedral Intermediate
Transition State Theory
Product details
- ISBN 9780824724498
- Weight: 2190g
- Dimensions: 178 x 254mm
- Publication Date: 01 Nov 2005
- Publisher: Taylor & Francis Inc
- Publication City/Country: US
- Product Form: Hardback
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The field of isotope effects has expanded exponentially in the last decade, and researchers are finding isotopes increasingly useful in their studies. Bringing literature on the subject up to date, Isotope Effects in Chemistry and Biology covers current principles, methods, and a broad range of applications of isotope effects in the physical, biological, and environmental sciences.
The authors first explain how kinetic, equilibrium, and anharmonic isotope effects are used to measure the ratio of reaction rates, the ratio between isotopes in thermodynamic equilibrium, and the geometric changes between molecules. The volume describes basic theories, including gas phase, simple condensed phase, small molecule studies, and applications of the Bigeleisen-Mayer theory before covering how isotopes affect molecular geometries, chemical bond breaking, formation and chemical dynamics, and hydrogen transfer. It explores novel, mass-independent isotope effects and problems encountered in hydrogen transfer, tunneling, and exchange. Authors also discuss isotope effects in organic and organometallic reactions and complex enzyme reactions and a unique chapter explores water isotope effects under pressure.
Written by internationally recognized researchers from 13 countries, some chapters summarize the perspective of a well-established subject while others review recent findings and on-going research that occasionally present controversial viewpoints using clear scientific arguments and discussion presented by all relevant authors. Isotope Effects in Chemistry and Biology brings together a wide scope of different perspectives and practical developments and applications into a comprehensive reference of isotope effects that reflect the most current state of the art.
Hans-Heinrich Limbach, Amnon Kohen
