Oxidation and Antioxidants in Organic Chemistry and Biology
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A01=Evgeny T. Denisov
A01=Igor B. Afanas'ev
activation energy calculation
Alkoxyl Radicals
Alkyl
Alkyl Radicals
antioxidant kinetics
antioxidant mechanism analysis in biology
Author_Evgeny T. Denisov
Author_Igor B. Afanas'ev
biological oxidative stress
Category=PNN
Category=PS
Category=PSE
CH Bond
Chain Termination
DMPO
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eq_isMigrated=1
eq_isMigrated=2
eq_nobargain
eq_non-fiction
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Final Proof Page
free
free radical intermediates
Hydrocarbon Oxidation
hydrogen
Hydrogen Atom
hydroxyl
kJ Mol1
Lipid Peroxidation
Liquid Phase Oxidation
Me2 CH
Microsomal Lipid Peroxidation
Mol L1
mol1
Mol1 S1
NADPH Oxidase
NH Bond
Nitroxyl Radical
organic reaction mechanisms
Oxygen Radical Production
page
peroxide
peroxyl
Peroxyl Radical Reactions
Phenoxyl Radicals
polymer oxidation processes
proof
radical
radicals
Sod Activity
Superoxide Production
Transition Metal
Product details
- ISBN 9780824753566
- Weight: 1973g
- Dimensions: 178 x 254mm
- Publication Date: 29 Mar 2005
- Publisher: Taylor & Francis Inc
- Publication City/Country: US
- Product Form: Hardback
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Providing a comprehensive review of reactions of oxidation for different classes of organic compounds and polymers, and biological processes mediated by free radicals, Oxidation and Antioxidants in Organic Chemistry and Biology puts the data and bibliographical information you need into one easy-to-use resource. You will find up-to-date information about mechanisms of action of antioxidants, their reactivity, reactions of intermediates, synergism, and antioxidants with cyclic mechanism action. Supplying useful, quantitative data in tables that make the information easy to find, the authors highlight the peculiarities of mechanisms involved in the oxidation of hydrocarbons, polymers, and different organic compounds.
The book provides tabulated values of strengths of C-H bonds of oxygen-containing compounds; of O-H bonds of hydroperoxides, alcohols, and acids; and of attacked antioxidant bonds. The authors collect and discuss over 3000 rate constants of different reactions of peroxyl radicals in oxidation and co-oxidation. They describe a new semiempiric theory of reactivity of reactants in elementary oxidative steps and the algorithm of calculation of activation energies, rate constants, and geometrical parameters of the transition states of free radical reactions. After elucidating the chemistry and kinetics of antioxidant action, the book covers oxidative processes that occur in biological systems.
Evgeny T. Denisov, Igor B. Afanas'ev
