Specific Interactions and the Miscibility of Polymer Blends
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A01=John F. Graf
A01=Michael M. Coleman
A01=Paul C. Painter
advanced materials science
APU
association model application
Author_John F. Graf
Author_Michael M. Coleman
Author_Paul C. Painter
Bernard Shaw
Calculated Solubility Parameters
Category=PNNP
Chemical Repeat Units
Copolymer Composition
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eq_isMigrated=1
eq_isMigrated=2
eq_nobargain
eq_non-fiction
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Equilibrium Constants
EVA Blend
EVA Copolymer
Favorable Intermolecular Interactions
Hydrogen Bonded
Hydrogen Bonded Carbonyl Groups
Hydrogen Bonded Systems
hydrogen bonding analysis
Infrared Spectroscopic Measurements
John F. Graf
LCST Behavior
Michael M. Coleman
Miscibility Window
Miscible Blend
Molar Attraction Constants
Molar Volume
Paul C. Painter
PEO Blend
phase diagram calculation
polymer miscibility modeling software
polymer thermodynamics
PVC Blend
San Blend
San Copolymer
Segment Information
Solubility Parameter Difference
Solubility Parameters
vibrational spectroscopy
Vinyl Phenol
Product details
- ISBN 9780367401511
- Weight: 453g
- Dimensions: 156 x 234mm
- Publication Date: 23 Sep 2019
- Publisher: Taylor & Francis Ltd
- Publication City/Country: GB
- Product Form: Paperback
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This book with software provides powerful tools for the analysis, prediction and creation of new polymer blends, an area of significant commercial potential. The R&D approaches and methods described in the book have attracted the interest of polymer R&D leaders in industry, and have been put into use in several major chemical companies. The companion set of computer programs speeds and facilitates work in this area.
FROM THE AUTHORS' PREFACE:
During the 1980's a steadily increasing number of compatible systems [polymer blends] have been reported. We believe that miscible mixtures will prove to be fairly common and the purpose of this book is to explore the circumstances in which single phase materials can be obtained. We will also describe a model for the phase behavior of these mixtures which we believe to have a predictive value, or be used as a practical guide to polymer miscibility.
Our approach is based on the use of association models which have until recently been largely ignored in treating hydrogen bonding in polymer mixtures. They have most frequently been applied to mixtures of alcohols with simple hydrocarbons, where the equilibrium constants used to describe association have most frequently been determined by a fit to thermodynamic data (e.g., vapor pressures, heat of mixing). In our work we have sought to, first, adapt this approach to a description of the phase behavior of polymer mixtures; second, develop spectroscopic methods that provide an independent measurement of the equilibrium constants.
Our purpose in this book is to explore and describe this approach and illustrate its broad utility. We address two overlapping yet different audiences. One would be primarily interested in the broad nature of this approach and the practical applications of a simple model. The second would be more interested in the derivations of the equations and some of the fundamental aspects of the spectroscopy of these systems.
Accor
Coleman, Michael M.; Painter, Paul C.; Graf, John F.
